1,1-Thicarbonyldiimidazole

Catalog Number	ACM6160652-2
CAS Number	6160-65-2
Structure
Molecular Weight	178.21 g/mol
Molecular Formula	C7H6N4S
Boiling Point	390.8 °C(760 mmHg)
Melting Point	98-102 °C(lit.)
Flash Point	190.1 °C
Density	1.39 g/mL
Application	11'-Thiocarbonyldiimidazole is a versatile reagent primarily used for deoxygenating carboxylic monosaccharide analogues and alcohols as well as diols when combined with specific reagents like tributyltin hydride and lithium aluminum hydride respectively It plays a critical role in organic and biochemical synthesis functioning as a safer alternative to thiophosphoryl chloride due to its rapidly displaceable imidazole groups Additionally it is key in synthesizing various compounds including thiosemicarbazones thioamides and certain imidazoles Its application extends to important chemical reactions such as the Corey-Winter olefin synthesis and the Barton-McCombie deoxygenation aiding in the preparation of complex molecules including those in enantioselective total synthesis and forming critical intermediates like cyclic thionocarbonates Furthermore TCDI's unique sulfur analogue structure is essential in macromolecular design processes like RAFT/MADIX polymerization enhancing its utility as a chain transfer agent for the preparation of trithiocarbonates xanthates and dithiocarbamates

Custom Reviews

November 30, 2024

A Versatile Reagent for Advanced Syntheses

1,1'-Thiocarbonyldiimidazole is excellent for deoxygenating alcohols and synthesizing complex molecules. It's pivotal in our lab's research on diol deoxygenation and polymerization, offering safer alternatives and precise results. Highly recommended!

※  Please kindly noted that this product is for research use only.

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