Catalog Number | ACM56310180 |
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CAS Number | 56310-18-0 |
Structure | |
Synonyms | CHLORO-DI-TERT-BUTYLSILANE;DI-T-BUTYLCHLOROSILANE;DI-TERT-BUTYLCHLOROSILANE;Di-tert-butylchlorosilane 99% |
Molecular Weight | 178.77 |
Molecular Formula | C8H19ClSi |
Boiling Point | 82-84°C45mm Hg(lit.) |
Flash Point | 103°F |
Density | 0.884g/mL at 25°C(lit.) |
Application | Extensive research has been conducted on alkoxysilanes as intramolecular hydrogen transfer agents, with a focus on di-tert-butyloxysilanes synthesized from di-tert-butylchlorosilane and the necessary alcohol. These compounds are highly effective and typically remain stable during column chromatography. By treating a γ-iodoallylic alcohol with NaH and t-Bu2SiHCl, the corresponding di-tert-butyloxysilanes can be obtained. Subsequent exposure to UV irradiation in the presence of 10% hexabutylditin facilitates the unimolecular chain transfer (UMCT) reaction of silicon hydrides, resulting in the production of reduced alkenes according to the provided equation (eq. 1). |
Effective and Stable Di-Tert-Butylchlorosilane for Research
Using di-t-butylchlorosilane in research has been a game-changer. It is stable to column chromatography and plays a crucial role in the unimolecular chain transfer reaction. The product has shown great results in reducing alkenes, making it a valuable asset in scientific research.
※ Please kindly noted that this product is for research use only.