Triethylsilicon hydride

Catalog Number	ACM617867-1
CAS Number	617-86-7
Structure
Molecular Formula	C6H16Si
Boiling Point	107108 °C
Melting Point	-157 °C
Flash Point	-6 °C
Purity	0.98
Density	0.728 g/mL
Application	Triethylsilicon hydride serves as a versatile reagent primarily used in the synthesis of alkylsilanes through the hydrosilation of olefins Its active hydride component makes it an effective reducing agent particularly in reactions such as the reduction of 2-chromanols It also facilitates various chemical transformations including the regioselective reductive coupling of enones and allenes Beckmann rearrangement of cyclododecanone oxime and redox initiated cationic polymerization Furthermore triethylsilicon hydride is employed for the selective reduction of alkenes in conjunction with trifluoroacetic acid This reagent is frequently chosen for its availability favorable physical properties and cost-effectiveness compared to other organosilicon hydrides making it suitable for numerous synthetic applications Its functions extend to hydrosilylations silane alcoholysis reduction of acyl derivatives to aldehydes radical chain reductions and reductive substitutions among others Triethylsilicon hydride is also capable of mediating palladium-catalyzed dehalogenation reactions and reducing primary secondary and tertiary chlorides bromides and iodides with the aid of iridium efficiently reducing multiple bonds azides imines nitro groups and aiding in the deprotection of benzyl and allyl groups Additionally it is utilized in the synthesis of a spiro-oxindole blocker for pain treatment and in facilitating the reductive amidation of oxazolidinones with amino acids to form dipeptides
Storage	Moisture Sensitive
HS Code	Hazardous for shipping
MDL Number	MFCD00009018
Packaging	10 g
Refractive Index	1.412

Custom Reviews

November 24, 2024

Reliable and Versatile Reductant for Organic Synthesis

Triethylsilicon hydride from Alfa Chemistry has been invaluable in my research. Its efficacy in hydrosilation and reducing complex structures has streamlined our synthetic processes, making it an essential reagent in our lab.

※  Please kindly noted that this product is for research use only.

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