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Fluorosilane

The chemical category of fluorosilane consists of organosilicon substances that hold silicon-fluorine connections which follow the chemical formulas R₃SiF or R₂SiF₂ (R stands for an organic group). Fluorosilane exists as a non-toxic gas that lacks color and odor and maintains stable chemical properties while being unable to sustain combustion. Fluorosilane serves multiple purposes throughout industrial production processes.

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What is Fluorosilane?

Fluorosilane is a silane compound composed of silicon and fluorine. Fluorosilane has a low boiling point and low density, and some fluorosilanes are in liquid state. The Si-F bond is highly stable and resistant to hydrolysis; it has strong surface activity and can achieve super hydrophobic and antifouling functions through the terminal fluorocarbon chain.

What are the Features of Fluorosilane?

Chemical Stability‌

Fluorosilanes have high resistance to hydrolysis and chemical corrosion.

Excellent Surface Properties‌

Fluorosilanes have ultra-low surface energy and self-cleaning properties.

Thermal Stability and Temperature resistance‌

Some fluorosilane-based materials can maintain stable performance in the range of -89°C to 232°C.

Fluorosilanes Products List

What are the Applications of Fluorosilane?

‌Industrial Material Additives

‌Fluorosilane can be used as rubber and coating modification and silicon steel protection.

Surface Treatment and Functional Coatings

‌Fluorosilane can be used as electronic device coatings and has self-cleaning and anti-fouling functions.

Electronics and Semiconductor Manufacturing

‌‌‌Fluorosilane can be used as a semiconductor material desiccant and is used in semiconductor production environments.

Precision Manufacturing and High-end Materials

As a key component of fluorosilicone materials, it is widely used in strategic industries such as new energy.

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Question and Answer

What is a fluorosilane coupling agent?

Fluorosilane coupling agents represent organic silicon compounds with fluorine-carbon chains that demonstrate low surface energy like fluorides together with silane coupling agents' reactivity. Typical representatives include: Heptafluorodecyltrimethoxysilane functions in both electronic coatings and glass self-cleaning applications. Perfluorooctyltriethoxysilane serves as an appropriate compound for water and oil repellent treatments on metal and ceramic surfaces.

What is fluorosilane coating?

Fluorosilane coating‌ is a high-performance coating with excellent weather resistance, corrosion resistance and self-cleaning ability. The core feature of this coating is its low surface energy, which makes it difficult for stains and dust to adhere, and the coating can maintain stability and protective effect even in extreme climate conditions. Fluorosilane coating is widely used in various fields, including: for high-rise buildings, bridges and other large infrastructure. It can also be used to protect various metal structures from wind and rain erosion, salt spray corrosion and ultraviolet radiation.

What are the general storage conditions and handling methods for fluorosilanes?

Fluorosilanes should generally be stored in a closed, cool and dry place away from air to prevent hydrolysis. When handling fluorosilanes, avoid contact with water because hydrolysis reactions can cause them to decompose. Heating in the presence of alkali will cause them to hydrolyze to form trimethylsilanol and its condensate hexamethyldisiloxane‌.

Case Study

Ultrathin Fluorosilane Films for Surface Modification of Biomedical Nanodevices

Bhushan, Bharat, Derek Hansford, and Kang Kug Lee. Journal of Vacuum Science & Technology A 24.4 (2006): 1197-1202.

Ultrathin coatings of fluorosilane films on silicon and polydimethylsiloxane (PDMS) help control the hydrophobicity of the surface and reduce or prevent unwanted protein adsorption or cellular interactions that are critical to the performance of most biomedical micro/nano devices. Surface modification using vapor deposition is becoming increasingly important for some biomedical nanodevices and has advantages over liquid deposition because the vapor phase can more efficiently penetrate into silicon nanochannels. Ultrathin films of four fluorosilanes were deposited on silicon and PDMS using vapor deposition and the deposition conditions for the optimal process were determined.

For the fluorosilane deposition, a steady-state chamber pressure was achieved by flow control of the carrier nitrogen gas and vacuum lines. The carrier gas was used to remove excess unreacted chemicals. The deposition process was followed by a 20-minute annealing step. After the deposition process was completed, the inlet/outlet valves were closed to isolate the glass tubes and the chamber was evacuated. After the deposition was completed, the bypass carrier gas line was opened to introduce pure nitrogen into the vacuum chamber to complete the removal of byproducts and unreacted chemicals. Finally, the samples were removed from the vacuum chamber and transferred to a vacuum desiccator until characterization.

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