2-Trimethylsilyl-13-Dithiane

Catalog Number	ACM13411422-3
CAS Number	13411-42-2
Structure
Molecular Weight	192.42 g/mol
Molecular Formula	C7H16S2Si
Purity	0.98
Application	2-Trimethylsilyl-13-dithiane serves as a versatile acyl anion equivalent facilitating a range of synthetic transformations It is a precursor to dithioketene acetals which are highly effective for both cationic and anionic cyclization processes When reacted with unsaturated ketones and aldehydes it forms vinyl dithioketene acetals that can act as dienes or be converted into substituted αβ-unsaturated alkyl ketones This compound also enables the general synthesis of acylsilanes through alkylation of its anion making it a valuable tool for creating complex molecular structures It engages in various reactions including Thioketene Acetals Cationic and Anionic Cyclizations Unsaturated Dithioketene Acetals and the Formation of Bis(acylsilanes) among others Moreover 2-Trimethylsilyl-13-dithiane can participate in Lewis base-catalyzed additions to electrophiles like carbonyl compounds and N-substituted aldimines and undergoes novel diazo transfer reactions to produce formal carbene adducts
Storage	Ambient temperatures.

Custom Reviews

November 28, 2024

Essential Acyl Anion Equivalent for Advanced Research Applications

User Experience: Using 2-Trimethylsilyl-1,3-dithiane in our research enabled efficient synthesis of acylsilanes. Its versatility in cyclization and addition reactions was invaluable. Highly recommend Alfa Chemistry for reliable quality in complex studies.

※ Please kindly noted that this product is for research use only.