Triphenylhydrosilane

Catalog Number	ACM789253-1
CAS Number	789-25-3
Structure
Molecular Formula	C18H16Si
Boiling Point	159163 °C(3 mmHg)
Melting Point	42-44 °C
Flash Point	76 °C
Purity	0.99
Application	Triphenylhydrosilane serves as a versatile reagent in various chemical reactions and synthetic processes It is utilized for catalytic hydrogen-deuterium exchange reactions involving silanes and can be oxidized using carbon nanotube-gold nanohybrids Also it undergoes hydrolysis when reacted with ruthenium complexes and participates in hydrosilylation to produce enolsilanes Moreover triphenylhydrosilane is instrumental in synthesizing bromosilanes and facilitates ozone oxidation of silyl-alkenes to yield α-O-silylated acyloin derivatives It is used in the synthesis of hydrido silyl and bis(silyl) bis(imidazolinylidene) nickel complexes Additionally triphenylhydrosilane is a more effective radical-based reagent for reducing organic halides compared to trialkylsilanes and performs comparably to tri-n-butyltin hydride in reducing enones to ketones demonstrating good selectivity in reducing cyclic hemiacetals It also converts O-acetyl furanoses and pyranoses to deoxy sugars and facilitates the formation of hexaphenyldisiloxane through reaction with aqueous alkali Similarly tristriphenylsilylbismuth can be produced by reacting triphenylhydrosilane with triethylbismuth under heat
Storage	Air Sensitive
HS Code	Non-hazardous for shipping
MDL Number	MFCD00003003
Packaging	25 g

Custom Reviews

November 01, 2024

Highly Effective Reagent in Synthesis and Reduction Reactions

Triphenylhydrosilane from Alfa Chemistry greatly enhanced my research. It was pivotal in successful hydrogen deuterium exchange and reducing organic halides effectively, providing excellent selectivity and reliability in our laboratory experiments.

※  Please kindly noted that this product is for research use only.

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